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Advancement in nanotechnology of polymers and fibers
By :   Dr. Faheem Uddin
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Man is not very old to forget the invention of wheel, and the wave of time is not out of the scene to find it hard when recalling the beginning of computer age. Now we are at the onset of new era of science that explores the behavior of material at their bottom, set new topics in technical applications of polymeric materials, and expose immense opportunities in the performance and application of materials.


Nanotechnology has currently received an exceptional interest of researchers, technology incubators and commercial organizations to step forward in introducing the materials having nanocomposite structure and new performance standards.


Investigating the smallest possible particles had provided the opportunity of exploring new performance standards for materials. New dimensions are appearing in material processing and applications in most disciplines of science and technology and the field of textile has no exception. From the production of synthetic fibers from polymer melt to the special finishing effects of fabric substrates, nanoparticles are occupying the positions in producing the composite structure for desired effects.


Atom is known to the world since the introduction of classical science age as an elementary unit of any material, however the functioning of material was perceived in most cases in terms of aggregate structures. The recent onset of nanotechnology is now demonstrating the material performance on the basis of very small particles that are having size range of fewer nanometers.


The word nano in nanotechnology has origin in Greek word nanos meaning dwarf (small). Prefix nano means one-billionth part, i.e. 10-9, for example one nanometer is one-billionth part of a meter. How large is one nanometer! Perhaps it can be imagined by the diameter of single human hair which is approximately 100,000 times greater than one nanometer. Nanoparticles are atomic assembly that exhibits outstandingly different behavior than the bulk of material. An example may be seen in ceramics which are known as brittle and rigid materials. A ceramic material can be made deformable when their constituent grain size is reduced to low nanometer range. Also, a small amount of nanoparticles of a substance when included in a polymer matrix having similar size range the resulting system exhibits an exceptional performance level (1).


Nanotechnologies can be perceived as the design, characterization, production, and application of structures, devices, and systems by controlling shape and size of material particles on nanometer scale (2). The origin of nanotechnology can be traced to a talk given by Richard Feynman on 29th December 1959 at the annual meeting of the American Physical Society at the California Institute of Technology, U.S.A., on the topic of There is Plenty of Room at the Bottom. Further, the term nanotechnology was introduced by Norio Taniguchi, Tokyo University, almost 15 years after in 1974. The concept was expanded by Eric Dreklor, MIT, USA in 1986 through his book Engines of Creation: the Coming Era of nanotechnology. Subsequently, nanoscience then became the study of phenomena and manipulation of materials at atomic (0.2nm approx), molecular or macromolecular scales (around 100nm).


Why to see that magnificent change in the performance of material at nanoscale! This is the result of relatively significant increased surface area-to-mass ratio. The same material becomes more chemically reactive and exhibits different physical properties. Moreover, below the particle size of 50 nm, the laws of classical physics follow quantum effects that result in different optical, electrical and magnetic performance relative to the large size structure of same material (2).


There is no single branch of science and technology or industry that is not affected by nanotechnology. The development and innovations in the next 10 years or so would even be showing stronger influence of nanotechnology on most materials we are surrounded. To date, it has accommodated the multiplication of applications in material manufacturing (more importantly in polymer modification and synthesis), and computer/electronic chips, medical diagnosis, health care, finishing formulations, energy, automations, biotechnology, packaging, space, aircrafts, protection and security.


 

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