FIGURE
|
PTT
|
PET
|
|
IV [dl/g]
|
0.8-1.2
|
0.55-0.65
|
|
TG [C]
|
50-60
|
76-80
|
|
TK [C]
|
80-120
|
130-150
|
|
TM [C]
|
226-229
|
254-258
|
|
Crystallization
|
non
|
1 h at 150C
|
|
Drying temp. [C]
|
125
|
160
|
|
Time [h]
|
6
|
6
|
|
Dew temp. [C]
|
-40
|
-25
|
|
Extrusion Zones [C]
|
240-270
|
280-300
|
|
Melt temp. [C]
|
255-265
|
285-295 in the die
|
Comparison of polymer properties and
process features for spinning
PTT and PET
Conclusion:
Unlike other introductions of new polymers to the industry,
the introduction of PTT was accompanied by powerful marketing activities from
the first. Shell has announced that it has a PDO production unit of 75,000t/a
capacity on stream. Shells PTT polymer production is estimated to be in the
range of 21,000t/a. Shells PTT activities are covered by the trade name
Corterra. In 1998, DuPont acquired the PDO production of Degussa in Wesseling, Germany. This plant is producing about 12,000t/a PDO with the option to expand
the capacity to 50,000t/a. DuPonts PTT activities are covered by the trade
name Sorona.
The
question of poly trimethylene terephthalate (PTT) is only appearing now and not
60 years ago, when it was invented, has many different answers. One reason is
that at that time of invention, poly ethylene terephthalate (PET) was found to
be the polymer with the broadest application potential in different industrial
fields, including films for video and audio, textile fibre, technical films and
packaging. Another reason was the limited avail-ability of 1,3-propanediol
(PDO), which was expensive. However, PDO is now playing the major role in the
industrial development of PTT.
References:
1) www.freepatentsonline.com/6495254
2) www.intota.com/multisearch.asp
3) www.technica.net/NF/NF1/eptt.htm
4) sciencelinks.jp/j-east/article
5) www.fbi.gov/hq/lab/fsc/backissu/july2001/houck.htm
6) www.wipo.int/pctdb/en/wo.jsp
7) www.swicofil.com/polytrimethyleneterephthalate.html
8) en.wikipedia.org/wiki/Polyethylene_terephthalate
9) www.springerlink.com/index/AV1DWAWEDCQPHTC3.pdf
10) jit.sagepub.com/cgi/content/refs/31/3/159
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