In normal circumstances, heat will flow through the garment
to the outer environment. With the presence of PCMs within the
garment, this flow is interrupted as the PCM absorbs or releases the
heatpreventing the heat access to the outer environment. In this way an active
thermal barrier (insulation) is created that is in addition to the normal
passive thermal barrier inherent in the garments design.
Burlington Worldwide (BWW), in partnership with Outlast
Technologies and Ciba, has created a finish that allows fabrics to adjust to
changes in temperature for more comfortable and versatile clothing. The
patent-pending technology, called Smart Fabric Technology, is built around
micro encapsulated phase-change materials called Thermocules. These materials
absorb and release heat for increased comfort without compromising the fabric's
inherent characteristics. A paraffin-PCM, for example, absorbs approximately
200 kilojoules per kilogram of heat to undergo a melting process. This high
amount of heat absorbed by the paraffin in the melting process is released into
the surrounding area during the cooling process starting at its crystallization
temperature. During the complete melting process, the temperature of the PCM as
well as its surrounding area remains constant. The excess heat generated
by a body in action is absorbed by the paraffin in the PCM which melts in
the process and stores the heat. Since the excess heat has been taken
away from the body, the undesired temperature increase concomitant with
the normal heating process does not occur. The same is true for the
crystallization process. During the entire crystallization process the
temperature of the PCM does not change either. The high heat transfer during
the melting process as well as the crystallization process without temperature
change makes PCM interesting as a source of heat storage.

The PCM is normally present in microcapsules, which can
resist wear and tear during the life of the garment. Microencapsulated PCMs can
either be distributed within fibers or coated onto the fabric. Whilst the
concept of using PCMs is clearly a very attractive one, there are still a
number of limitations. Acrylic is the only commercially available fiber that is
compatible with PCMs, and there is an upper limit to the amount of PCM that can
be incorporated in the fibers before tensile properties are appreciably
reduced. Where PCMs have been coated onto fabrics, fabric hand may be
compromised, and durability to abrasion during wear and to washing and
dry-cleaning may be lowered.
The selection and incorporation of PCMs in textiles requires
care. The most important consideration is the actual temperature of the phase
change, and in garments this should normally be 30-35 C, close to the bodys
temperature. Other key factors include cost, toxicity and availability. The
initial applications of the finish will be in fabrics for active wear apparel.
Future planned applications include men swear, uniform and barrier products.