Obtained
results are suggesting that because of the reduction of formaldehyde release
noticed on conventional N-methylole based products, which are cheaper and more
reactive, but abandoned because of the formaldehyde problem, can be used.
Further interesting investigation to be performed would include improvement of molecules polarity degree. In this way further formaldehyde release can be enhanced
while its quantity is further reduced or completely eliminated from the treated
material.
3.2.
Water and -oil repellent finishing
Comparing
the results of water and oil repellent finishing, shown in tables 4 and 5, improvements of water repellency are noticeable in a case of microwave treatment. With both
thermal treatments effects of the oil repellency are similar.
Improvements of the repellency effects are explained with the impact of the heated cylinder, which
is included in the passage of the textile material for additional improvement of FC orientation. Improvements of the repellency effects obtained with additional
thermal treatment (hot-ironing) after the tenter curing have shown that the
reaction was not completely finished, especially when thicker material was
treated.
Effectiveness
of the repellency after the dry-cleaning is very good with both applied curing
methods.
3.3. Flame retardant finishing
Results of flame retardancy, showed in tables 6 and 7, obtained by
microwave inducement are equally good compared to conventional curing method.
Application of BTCA for binding purposes gave equaly good FR effects as
conventional MF cross-linking agent which is ecologically unacceptable. Both
treating baths gave good results of flame retardancy, slightly lower after the
microwave treatment. Effectivenes of flame retardancy was tested after the
washing, and results have revealed some decrease. Decrease of the results after
the washing is more noticeable at the samples which were treated by microwaves,
but they are still satisfying. Obtained durability to washing of samples
treated by microwaves is confirming sufficient crosslinking of OFR molecules
with celullose molecules.
Conclusions
Results of performed investigations are indicating that microwaves are
suitable for drying as well as curing processes of textile finishing. From the
results of textile finishing treatment with different finishing agents further
conclusions can be made:
Application
of microwaves in Durable Press finishing offers significant improvement in comparison to the classical curing method performed at tenter.
Microwave
treatment reduces formaldehyde release.
In
water and oil-repellent finishing with FC polymers MW gives certain improvements.
In
flame retardant finishes with organophosphorus reagents MW are showing equally
good efficiency.
Application
of MW in drying and finishing process gives certain improvements of effects,
but its suitability should be preliminary tested for each reagent.
Favorable
effects obtained by MW and treatments cost are indicating good possibility of
its implementation in praxis. After the conclusion of laboratory experiments,
construction of an industrial microwave device is to be expected.