Main Objectives in Environmental Protection by
Catalysis:-
a) Pollution prevention by developing energy-saving
processes free of pollution formation.
b) Decreasing pollution by achieving higher selectivity in
fuel and chemical manufacture
c) Decreasing pollution by developing new and improved
catalytic processes for removal of pollutants.
d) Developing competitive processes for production of
hydrogen, chemicals and energy sources, providing reduced CO2 production.
e) Research: production of major products with greater
energy and feedstock efficiency and with improved environmental issues.
Where catalysis plays a major role in the
future?
- Reformulated fuels
- NOx, SOx; CFCs, VOCs, CO,
methane, automotive exhaust gases O3, N2O, CO2
- Byproducts from chemical
industry
- Odor control
- Toxic waste gas purification
Driving forces:
- Environmental concerns
- More selective catalysts to improve yields and to
reduce byproducts formation
- Replacement of liquid acids and aluminum chloride with
solid acids, based on zeolite chemistry or other amorphous acidified
silica alumina.
Membrane Separation
As the cost of wastewater disposal increases more emphasis
is being placed upon the recovery and recycling of valuable chemicals contained
within these streams. Membrane technology is a more recent development that can
be used in conjuction with extraction solvents to extend the range of
conditions under which such processes are available.1 The separation of
distillery grain stillage was carried out on the micro filtration and ultra
filtration ceramic three-channel membranes with pore diameter range from 1.4
μm to 15 kDa. In separation sequence the ions were recovered from
permeates by electrodialysis.4, 5. The process was evaluated from the point of
view of the mass balance and the dynamics (total separation time, the decline
of the filtration effort made on the ceramic membranes, fouling effect, etc.).
With this process we try to get some advantages over the conventional process
in terms of eliminating both land and energy costs for the wastewater treatment
process and improving the quality of the discharge water.
Reverse Osmosis
When a permeable membrane separates a dilute solution, the
osmotic pressure drives the water molecules from the dilute solution, through
the membrane to establish equilibrium. This natural response is reserved in the
reverse osmosis process, where the waste water containing dissolved salts are
filtered through a semi-permeable membrane such as cellulose acetate at a pressure
higher than the osmotic pressure.