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Nanoselenium cloth absorbs mercury from broken CFL

30 Jun '08
5 min read

“These patents represent how Brown University translates fundamental research into an application that can have an impact on society – in this case, a technology that could protect households from mercury exposure and that could also energize green business growth,” says Clyde Briant, vice president for research at Brown.

The inspiration for the invention followed the discovery by Hurt, Johnson and fellow Brown researchers that a variant of a substance called nanoselenium – a form of selenium, a trace element used in diet supplements, among other products – absorbed virtually all the mercury emitted from a broken CFL. That finding appears this week in the online edition of Environmental Science & Technology. It is the first scientific paper that measures the timing and extent of mercury released from broken CFLs and that reveals the mercury-absorption potential of various nanomaterials, the researchers say.

The engineers tested 28 substances in all. Their experiments showed that one type of nanoselenium absorbed mercury vapor the most effectively. The selenium atoms bond with the mercury atoms to form mercury selenide (HgSe), a stable, benign nanoparticle compound, Hurt says.

The nanoselenium “just loves mercury,” Hurt adds.

In controlled experiments, the scientists found that 99 percent of mercury vapor from a CFL broken in a sealed chamber was mopped up by nanoselenium in concentrations ranging from 1 to 5 milligrams.

The small amount needed to capture the mercury vapor bodes well for manufacturing mercury-absorbent cloths or lining at a low cost, Hurt says. The precise manufacturing costs will need to be determined by interested companies.

The National Institute of Environmental Health Sciences Superfund Basic Research Program funded the research.

The first prototype created by the Brown team is a three-layered cloth that is attached to the packaging or box containing the CFLs. The nanoselenium-coated layer would be sandwiched between the cardboard packaging and a cloth on the inside of the box containing the bulbs. The extra layers prevent people from coming into contact with the nanoselenium layer.

If a bulb breaks, the user simply undoes the packaging and lays it on the spot where the break occurred. The absorbent material is effective on different surfaces, including carpets and hardwood floors. “It works like a charm,” Hurt says.

The second prototype incorporates the same layering and is fitted into a small, sealable plastic bag. The lining absorbs the mercury in the sealed bag, preventing it from escaping.

“More work is needed,” Hurt says, “but this appears to be an inexpensive solution that can remove most of the safety concerns associated with CFL bulbs.”

Brown University

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