August 30, 2008


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Ionic crosslinking of cotton
By  : Peter J. Hauser, C. Brent Smith, Mohamed M. Hashem

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Conclusions


Wrinkle resistance in cellulosic fabrics can be achieved with ionic crosslinks. Carboxymethylated woven cotton fabric treated with cationized chitosan showed significant increases in wrinkle angle recovery without strength loss. This process allows for enhanced wrinkle resistance without the chance of formaldehyde release.


References


  1. Daul, G., et al, Studies on the Partial Carboxymethylation of Cotton, Textile Res. J., 22(12), 1952, p 787.
  2. Hashem, M. et al, Synthesis of Reactive Polymers and Their Applications to Cotton Fabrics as Permanent Size, Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular and Liquid Crystals, 353, 2000, p 109.
  3. Kim, Y. et al, Synthesis of a Quaternary Ammonium Derivative of Chitosan and Its Application to a Cotton Antimicrobial Finish, Textile Res. J., 68(6), 1998, p 428.
  4. Peterson, Harro, Cross-Linking with Formaldehyde-Containing Reactants, Chapter 2 in Functional Finishes, Volume II, Part B; Lewis, M.; Sello, S. B. Eds.; Dekker, New York, 1983; p 200.
  5. Racz, I. et al, Crystallinity and Accessibility of Fiberous Carboxymethyl Cellulose by Pad-Roll Technology, J. Applied Poly. Sci., 62, 1996, p 2015.
  6. Racz, I. and Borsa, J., Carboxymethylated Cotton Fabric for Pesticide-Protective Work Clothing, Textile Res. J., 68(1), 1998, p 69.
  7. Racz, I. et al, Fiberous Carboxymethyl Cellulose by PAd Roll Technology, Textile Res. J., 65(6), 1995, p 348.
  8. XiQuan, L. et al, Kinetics of the Carboxymethylation of Cellulose in the Isopropyl Alcohol System, Acta Polymerica, 41(4), 1990, p 220.
  9. Yang, C. et al, Nonformaldehyde Durable Press Finishing of Cotton Fabrics by Combining Citric Acid with Polymers of Maleic Acid, Textile Res. J., 68(5), 1998, p 457.
  10. Yang, C. and Wei, W., Evaluating Glutaraldehyde as a Nonformaldehyde Durable Press Finishing Agent for Cotton Fabrics, Textile Res. J., 70(3), 2000, p 230.


Acknowledgment


The authors thank Dow Chemical Company for financial support and nitrogen analyses.



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Latest Comment

really nice information, with stringent norms for textiles and formaldehyde release this info is very useful
 navnath

 
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